(E)-2-Methoxy-9-(2-methoxy-9H-xanthen-9-ylidene)-9H-xanthene
نویسندگان
چکیده
The title compound, C28H20O4, was synthesized by a bimolecular Zn-HCl reduction in glacial acetic acid using the meth-oxy-substituted xanthone as a starting material. The crystal structure shows that the 2,2'-meth-oxy-bixanthenyl-idene unit is an E-type conformation anti-folded conformer. The mol-ecule lies on an inversion center. The meth-oxy group is almost coplanar with the attached benzene ring, with a C-O-C-C torsion angle of 179.38 (14)°.
منابع مشابه
9-Methoxy-9-(2-methoxyphenyl)-9H-xanthene
In the title compound, C(21)H(18)O(3), the xanthene system and the meth-oxy-phenyl ring are practically orthogonal with a dihedral angle between their mean planes of 89.27 (3)°. The meth-oxy group attached to the phenyl ring makes a C-O-C-C torsion angle of 11.56 (18)°. In the crystal, mol-ecules are linked by C-H⋯O inter-actions into chains along [010]. Weak C-H⋯π inter-actions also occur.
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